that sodium borohydride is strongly alkaline and corrosive. Do not allow sodium borohydride to come into contact with concentrated acids or oxidizing agents. SDS Sodium borohydride SDS Safety Data Sheet for Sodium borohydride 818823 Material Safety Data Sheet or SDS for Sodium borohydride 818823 from Merck for download or viewing in the browser. Do not use mouth-to-mouth method if victim ingested . - Find MSDS or SDS, a COA, data sheets and more information. Product name : Sodium borohydride Product Number : 452882 Brand : Aldrich CAS-No. IDENTIFICATION OF THE PRODUCT AND THE COMPANY Product Name : Sodium Borohydride Powder Use : Research and Development Address : Nanoshel LLC 3422 Old Capitol Suit 1305 Willmington DE - 19808 United States Emergency : +1.532.253.9878 2. - Shipped use reliable shipping services . Contact EH&S Fire & Life Safety, (858) 822-5706 or 534-3531, if you have questions about fire extinguishers. I think the hazards are over exaggerated in this msds, as the material is really quite tame when compared against other hydrides, that explode when contacting water. Immediate medical attention is required. : 124-41-4 1.2 Relevant identified uses of the substance or mixture and uses advised against Use dry chemical, carbon dioxide or alcohol-resistant foam. Pay attention to official safety regulations (see also: "Transport Regulations" and "GHS Hazard Pictograms"). Safety Data Sheet for Sodium borohydride 818823 Material Safety Data Sheet or SDS for Sodium borohydride 818823 from MilliporeSigma for download or viewing in the browser. Spontaneous ignition can result from solution of sodium borohydride in dimethylformamide. Sodium borohydride Revision Date 24-December-2021 Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. May damage the unborn child Precautionary Statements Prevention Make sure a Type D fire extinguisher is available. CID 2724942 (Triacetoxyborohydride) Component Compounds. Formula: NaBH 4. Proper Shipping Name: SODIUM BOROHYDRIDE Hazard Class: 4.3 UN/NA: UN1426 Packing Group: I Information reported for product/size: 100G International (Air, I.C.A.O.) -----Proper Shipping Name: SODIUM BOROHYDRIDE Hazard Class: 4.3 UN/NA: UN1426 Packing Group: I Information reported for product/size: 100G 15. Sodium borohydride Revision Date 24-Dec-2021 General Advice Immediate medical attention is required. Sodium borohydride is an inorganic compound whose chemical formula is NaBH 4. safety hazards of Sodium Borohydride to potentially exposed workers. . Chemist 1965]. COMPOSITION & INFORMATION ON INGREDIENTS Identification Number: UN1426. (a) Write a balanced equation for the reaction of \\mathrm{NaBH}_{4} with \\mathrm. . - Normally Posted/Shipped on the day of purchase. Packing Group: I. Strong reducing agent. . Material Safety Data Sheet Sodium borohydride sc-215866 Hazard Alert Code Key: EXTREME HIGH MODERATE LOW Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Sodium borohydride STATEMENT OF HAZARDOUS NATURE CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200. Sodium borohydride, also known as sodium tetrahydroborate, has the chemical formula Na B H 4. MP Biomedicals, LLC www.mpbio.com WHMIS hazard class: B6 reactive flammable material D2b toxic materials : : IMDG/IMO Proper shipping name: Sodium Borohydride IMDG - Hazard Classifications IMDG class or division = 4.3 IMDG - Regulated Substances UN1426 Components U.S. The thermal stability of sodium borohydride (NaBH4) in dimethylacetamide (DMA) was examined by comparison with NaBH4 in dimethylformamide (DMF), which is known to cause a violent runaway reaction. #1. Sodium tetrahydrobor ate. Details of the supplier of the safety data sheet Appearance: white solid. Regulatory Information Molecular Weight. : S678-10; S678-25 CAS-No 16940-66-2 Synonyms SBH; Sodium tetrahydroborate (Powder) Recommended Use Laboratory chemicals. Storage Under exclusion of air and humidity sodium borohydride has unlimited shelf life (decomposition is less than 0.1 % per year). . Inhalation Remove to fresh air. Safety precautions: Sodium borohydride is toxic and corrosive. Sodium borohydride (NaBH4) is the most commonly available borohydride, synthesized by reacting methylborate with sodium hydride in mineral oil. When handling sodium borohydride, nitrile or neoprene gloves, safety goggles and a flame retardant lab coat have to be worn. (USCG, 1999) Reactivity Profile SODIUM BOROHYDRIDE is a powerful reducing agent. Chemist 1965]. Gov. Fire Hazard Behavior in Fire: Decomposes and produces highly flammable hydrogen gas. Bulk solutions of sodium borohydride are often prepared with excess sodium hydroxide, which is corrosive. Sodium borohydride | NaBH4 or BH4.Na or BH4Na | CID 4311764 - structure, chemical names, physical and chemical properties, classification, patents, literature . And the toxicological properties have not been fully investigated. NO foam. Safety Information. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Revision Date: July 6, 2016. Immediate medical attention is required. Description. Sodium borohydride (NaBH4) is a mild reducing agent that is typically used to reduce aldehydes and ketones to their respective alcohols. . - Packed in good quality packing. Sodium borohydride 16940-66-2 100 Toxicological Data on Ingredients: Sodium borohydride: ORAL (LD50): Acute: 160 mg/kg [Rat]. 5.3 Special protective actions for fire-fighters Use dry sand, dry powder. (USCG, 1999) Health Hazard Solid irritates skin. Borohydrides are versatile reducing agents with a wide variety of applications and benefits. Identification Product Name Sodium borohydride Cat No. Sodium borohydride. Fire Hazard Behavior in Fire: Decomposes and produces highly flammable hydrogen gas. CAS Number: 16940-66-2 . (USCG, 1999) Reactivity Profile SODIUM BOROHYDRIDE is a powerful reducing agent. Inhalation Remove to fresh air. In its elemental form, sodium has a silvery-white metallic appearance. Immediate medical attention is required. . Sodium was discovered and first isolated by Sir Humphrey Davy in 1807. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. We aims to provide a complete knowledgeable report so that . See Page 1. Inhalation of sodium hydroxide can also result in inflammation of the respiratory tract leading to lung problems like pulmonary edema. Keep the containers in a cool, dry and HAZARD SUMMARY Sodium borohydride is a white to grayish crystalline powder. Uses advised against No Information available Details of the supplier of the safety data sheet Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. When apply it, we should prevent dust, increase ventilation or wear protective masks. Nucleophilic addition of hydride ion from sodium borohydride is an inexpensive alternative method for the Baylis-Hillman reaction to form [E]--methylcinnamic acids. In our laboratory, sodium borohydride is used as a reducing agent and is prepared as aqueous or alcoholic solution. It has the formula NaBH4, which is made up of Sodium (Na), Boron (B), and Hydrogen (H). Gov. Chem. Do not use mouth-to-mouth method if victim ingested or . This excellent reducing agent is clean, efficient, but slightly expensive. Sodium borohydride burns in air [Lab. : 16940-66-2 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Industrial & for professional use only. Water is an oxygen hydride consisting of an oxygen atom that is covalently bonded to two hydrogen atoms It has a role as an amphiprotic solvent, a member of greenhouse gas, a human metabolite, a Saccharomyces cerevisiae metabolite, an Escherichia coli metabolite and a mouse metabolite. NaBH4, sodium borohydride, CAS 16940-66-2 Safety: R14/15, R34, R24/25 Handling and storage Handling: Avoid contact with skin, eyes and clothing. SAFETY DATA SHEET Creation Date 29-January-2010 Revision Date 24-December-2021 Revision Number 5 1. Harmful if swallowed, inhaled, or absorbed through the skin. Fever, sneezing, runny nose, sore throat, and pneumonia are some of the severe consequences of coming in contact with this chemical. Sodium borohydride is a moisture-sensitive substance. COA/MSDS: CONTACT US sodium borohydride, ref. When sodium borohydride is in a strongly basic solution (at or above pH 10), it is stabilized against reaction with water, although addition of water may still be exothermic due to heat of solvation. Causes eye and skin burns. sodium borohydride 137141-62-9: sodium borodeuteride 15681-89-7: sodium . It is widely used in Chemistry labs as it is safer than other reagents for reduction. 16940-66-2, EC Number 241-004-4. Material Safety Data Sheet Version 4.3 Revision Date 02/04/2013 Print Date 03/19/2013 1. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House If you would store it without taking special precautions, the powder will form a cake and loose some of its reductive strenght. Hazards Reactivity Alerts Strong Reducing Agent Air & Water Reactions When sodium borohydride is in a strongly basic solution (at or above pH 10), it is stabilized against reaction with water, although addition of water may still be exothermic due to heat of solvation. . Potential Chronic Health Effects: Extremely hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. It is an oxygen hydride, a mononuclear parent hydride and an inorganic hydroxy compound. Catalog Number 818823 Product Name Sodium borohydride Select Language If you are not able to see the SDS please use this link to download it: Download SDS 1. ALWAYS stay away from tanks engulfed in . Tel : 91 22 4268 5800 Fax : 91 22 4268 5801 Website : www.srlchem.com Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-10295 Be sure the reaction solution has a pH of 10 or higher when using sodium borohydride. sodium hydroxide solution Revision Date 25-Dec-2021 Hazard Statements May be corrosive to metals Harmful if swallowed Causes severe skin burns and eye damage May cause respiratory irritation May damage fertility. Contact with sodium borohydride will cause sore throat, cough, tachypnea, headache, abdominal pain, diarrhea, dizziness, conjunctival hyperemia, and pain. The presence of the electron-withdrawing cyano (CN) group makes it less reactive than sodium borohydride ( NaBH4 ). NO water. Proper Shipping Name: Sodium Borohydride The above information is believed to be correct, but does not purport to be all inclusive and shall be used only as a guide. If ingested can form large volume of gas and lead to a gas embolism. : 16940-66-2 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Synthesis of substances 1.3 Details of the supplier of the safety data sheet Company : Sigma-Aldrich Inc. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. NFPA SUPPLIER Company: Santa Cruz Biotechnology, Inc . It is the sixth most abundant element, making up 2.6 % of the earth's crust. Sodium Borohydride Safety Data Sheet (SDS) SDS #: 712.5. NaBH4 is sometimes used to reduce esters to alcohols but the reaction is generally slow. Sodium borohydride is a source of hydrogen or diborane, which are both flammable. Various approaches for qualitative and quantitative monitoring of sodium borohydride have been explained. ALWAYS stay away from tanks engulfed in fire. (USCG, 1999) Health Hazard Solid irritates skin. It is soluble in methanol and water, but reacts with both in the . The sodium atom has a radius of 185.8 pm and a Van der Waals radius of 227 pm. 211.94. Companies that count on Sodium Borohydrides, count on us. Avoid contact with sodium borohydride and do not breathe its dust. PRODUCT AND COMPANY IDENTIFICATION Product name : Sodium borohydride Product Number : 480886 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Most metal hydrides react violently with water. Hydrolysis of sodium borohydride (NaBH 4) offers substantial applications in the production of hydrogen but requires an inexpensive catalyst.Herein, silica (SP) and phosphorylated silica (SP-PA) are used as a catalyst for the generation of hydrogen from NaBH 4 hydrolysis. Articles of sodiumborohydride are included as well. It is employed as a precursor for producing other metal borohydrides. NFPA A several year old 100 mL glass bottle which had originally contained 25g of the complex hydride exploded while being opened a few hours after the previous opening to remove a portion. Property Value; Hazard Class: 4.3: Package Group: I: UN ID: UN1426: Remove Product. Sodium borohydride is stored in a sealed container, away from moisture and water. MATERIAL SAFETY DATA SHEET 1. SODIUM METHOXIDE CAS NO 124-41-4 MATERIAL SAFETY DATA SHEET SDS/MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name : Sodium Methoxide CAS-No. At lower pH levels, sodium borohydride reacts exothermically with water to generate flammable hydrogen gas. Company Identification: Acros Organics N.V. One Reagent Lane Fair Lawn, NJ 07410 For information in North America, call: 800-ACROS-01 For emergencies in the US, call . Sodium cyanoborohydride (NaBH3CN) is a mild reducing agent that is commonly used in reductive aminations. Sodium borohydride Safety Profile Ltd. Andheri (East), Mumbai - 400 099. What statements about the possible hazards of sodium borohydride are correct? DOT - Appendix B - Marine Pollutan U.S. Diana M. 12:00 am Report Abuse. Hazard Class: 4.3. Very hazardous in case of skin contact (corrosive). Fire Hazard Behavior in Fire: May decompose and produce highly flammable hydrogen gas. Sodium borohydride is a white to grayish crystalline powder. Sodium Triacetohydroborate, Triacetohydroborate Sodium Salt. Sodium borohydride (CAS NO.16940-66-2) hasn't been listed as a carcinogen by NTP, IARC, ACGIH, or CA Prop 65. Sodium borohydride or Sodium tetrahydridoborate or Sodium tetrahydroborate: CAS Number: 16940-66-2, EINECS EC Number: 241-004-4, Molecular Formula: NaBH4, Molecular Weight: 37.83, HS Code ---** How big is your requirement or how small We serve it all. The heat may ignite the hydrogen, the solvent, and surrounding combustible materials [Haz. Also used as a catalyst in the ammonia borane dehydrogenation. . Sodium borohydride MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Identification Product Name Sodium borohydride Cat No. Sodium borohydride. You can see actual entry in RTECS for complete information. Molecular Formula H 4 BNa; Average mass 37.833 Da; Monoisotopic mass 38.030376 Da; ChemSpider ID 26189 - Charge. Sodium borohydride TraceSELECT, for the determination of hydride formers by AAS, 99%, CAS Number: 16940-66-2,(71321 Fluka).Shop now or request a quote. Data 1966]. Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages . Sodium borohydride is an odorless white to gray-white microcrystalline powder which often forms lumps. It is decomposed by water to form sodium hydroxide, a corrosive material, and hydrogen, a flammable gas. MATERIAL SAFETY DATA SHEET SODIUM BOROHYDRIDE 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS Name: Sodium borohydride Company Identification: Sisco Research Laboratories Pvt. Immediate medical attention is required. . Wear suitable . Sodium borohydride, also known as sodium tetrahydridoborate and sodium tetrahydroborate, is an inorganic compound with the formula NaBH4. Water, acid, or high temperatures can liberate flammable hydrogen gas. Sodium borohydride sodium boranate sodiumborohydride Related Compounds: More. Information added from Borohidruro de sodio. SAFETY We constantly carry out risk analyses for each infrastructure, defining safety levels and implementing corrective measures promptly wherever they are needed. Safety: 15-20/21/22-35 Alfa Aesar 87659, 88983: 15-23/24/25-34 Alfa Aesar 13432, 35788, 38788, 87659, 88983: Product name : Sodium Borohydride CAS-No. Very hazardous in case of skin contact . Sodium borohydride is used as a reducing agent in the synthesis of gold nanoparticles. Ulceration and scarring of skin are some of the most commonly observed hazards . ho Sodium borohydride can have a violent reaction with acids, Sodium borohydride is flammable. As North America's leading borohydride supplier, Ascensus Specialties has the capacity, knowledge, and experience to meet growing demand and deliver specialized solutions for our customers. Sodium borohydride is used as a reagent in the reduction of amino acids and their derivatives. Safety Profile Ltd. Andheri ( East ), Mumbai - 400 099 also result in inflammation the! Revision Date 02/04/2013 Print Date 03/19/2013 1 oxidizing agents stored in a sealed container, away from and! 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And humidity sodium borohydride Revision Date 24-December-2021 Eye contact Rinse immediately with plenty of water, sodium borohydride hazards or. A source of hydrogen or diborane, which is corrosive also under the eyelids, for at least 15.! Specifications, safety Data Sheet ( SDS ) SDS #: 712.5, dossiers, brochures other! Its elemental form, sodium borohydride is flammable uses advised against Use dry,... Can also result in inflammation of the earth & # x27 ; s crust like pulmonary edema variety... So that, Mumbai - 400 099 or absorbed through the skin, or, occasionally, blistering [ ]. Hydride, a corrosive material, and hydrogen, a corrosive material, surrounding. 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